Ti segregation at CoSi grain boundaries

Segregation of Interstitial Impurities at Grain Boundaries in Transition Metals

Anisotropy of Segregation at Grain Boundaries and Surfaces

The purpose of this article is to review analytical models of the anisotropy of segregation to grain boundaries (GBs) and surfaces, and to evaluate their predictions. A summary of Gibbsian interfacial thermodynamics is provided as an introduction to the topic. This is followed by a historical overview of previous analytical models. A recently developed model of the dependence of GB segregation ...

SEGREGATION AT SPECIAL GRAIN BOUNDARIES IN Fe-Si ALLOY BICRYSTALS

The segre ation of silicon to the C=3, 112) and C=S, (013) symmetrical grain boundaries 1 was studied in well-fefined bicrystals of an Fe-l .9 at%Si alloy annealed in the range 773 1173 K using Auger electron spectroscopy. The segregation enthal y, AI1 = -8.1 * 0.5 kJ/mol, and entropy, AS = -69 r 0.4 i/(mol K), were determined for the (013f grain boundary in the temperature range 973 1173 K. Fo...

Layering transitions at grain boundaries

We review various simplified models that have been advanced to describe layering (complexion) transitions at grain boundaries in multicomponent solids. In particular, we first outline lattice-gas, off-lattice atomistic and thermodynamic models that have been employed to investigate phase-like behavior at segregated grain boundaries. The results of these investigations are summarized in the form...

Segregation of calcium to magnesium oxide grain boundaries

Grain boundary (GB) segregation has been measured in Ca-doped MgO by examining intergranular fracture surfaces with Auger electron spectroscopy. The measurements reveal several interesting features. The composition of any given GB on the fracture surface is almost uniform, except for small variations due to deviations from planarity. There is a strong anisotropy of GB composition, which can amo...